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Characteristics of Acids and Bases

Key definitions

  • Bases are oxides and hydroxides of metals. They neutralize acids.
    • Examples: CuO (copper oxide) and NaOH (sodium hydroxide)
  • Alkalis are soluble bases. They can dissolve in water to release hydroxide ions.
  • Salts are ionic compounds formed when the hydrogen ions, H+ in an acid are completely or partially replaced by a metal ion or an ammonium ion, NH4+.

The effect of acids and alkalis on litmus, thymolphthalein, and methyl orange

IndicatiorColor in AcidColor in AlkaliColor in Neutral
LitmusRedBluePurple
ThymolphthaleinColorlessBlueColorless
Methyl orangeRedYellowOrange

Chemical reactions of bases

  1. base + acid -> salt + water
  2. base (alkali) + ammonium salt -> salt + water + ammonia gas

Ions, pH, and universal indicator

Ions

  • Aqueous solutions of acids contain hydrogen (H+) ions.
  • Aqueous solutions of alkalis contain hydroxide (OH-) ions.

pH and universal indicator

  • Universal indicator changes color gradually depending on the concentration of H+ ions in a solution:
    • pH 0 to 6 (acidic): A high H+ conc. corresponds to lower pH numbers. For universal indicators, acidic solutions turn deep red/orange, meanwhile weak acids turn yellow/light green.
    • pH 7 (neutral): Equal conc. of H+ and OH- ions. Universal indicator turns green.
    • pH 8 to 14 (alkaline): Higher OH- conc. corresponds to higher pH numbers. Turns blue/deep purple.

Ionic equation for neutralization

  • The equation for the neutralization reaction between an acid and an alkali to produce water: H+ (aq) + OH- (aq) -> H2O (l)

Proton transfer

  • Acids are proton donors.
  • Bases are proton acceptors.

Acid strength vs. solution concentration

  • Strong/weak and concentrated/dilute describe completely different properties.
    • Strength refers strictly to the percentage of acid molecules that split into ions when dissolved into water.
  • A strong acid is an acid that is completely dissociated in aqueous solution.
    • Every single acid molecule breaks apart to release H+ ions.
    • An example is hydrochloric acid. HCl (aq) -> H+ (aq) + Cl- (aq)
  • A weak acid is an acid that is partially dissociated in aqueous solution.
    • Only a tiny fraction of the molecules split into ions. The rest remain intact as whole molecules.
    • An example is ethanoic acid. CH3COOH (aq) ⇌ H+ (aq) + CH3COO- (aq)